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陈贵华
发布时间: 2017-07-11 08:33:22   作者:学院办公室   来源: 本站原创   浏览次数:

一. 教育经历

1.2009/9–2012/6 中国科学院成都有机化学研究所,有机化学,博士,导师:廖建 研究员

2.2006/9–2009/6 西南大学,有机化学,硕士,导师:彭云贵 教授

3.2002/9–2006/6 西南大学,化学,学士

 

二. 科研与学术工作经历

1. 2014/7-至今,西南大学,化学化工学院,讲师

2. 2015/8-2017-8,西南大学,博士后,合作导师:彭云贵 教授

2. 2012/7-2014/6,北京大学,博士后,合作导师:施章杰 教授

 

三. 研究方向

合成方法开发及生物活性化合物合成

四. 主持项目

  1. 国家自然科学基金青年项目,(项目编号:21502156),催化不对称串联反应合成手性3-取代黄烷酮类化合物的研究,2015/1-2018/12,项目经费25万,在研,主持

2. 博士基金/引进人才计划项目,(项目编号:SWU114078),铁作为路易斯酸催化的不对称反应研究,2015/1-2017/12,项目经费5万,在研,主持

3. 中央高校基本科研业务费专项资金项目 (项目编号:XDJK2015C102),铁作为路易斯酸在不对称碳-碳键形成反应中的应用研究,2015/5-2017/12,项目经费5万,在研,主持

4. 中国博士后科学基金(项目编号:2012M520102),通过碳-氢键活化合成3-羟基氧化吲哚化合物,2012/11-2014/6,项目经费5万,已结题,主持

5. 中国博士后科学基金,(项目编号:2015M582494),动态动力学串联反应合成手性3-取代黄烷酮的研究2015/11-2017/7,项目经费5万,在研,主持

 

五. 代表性研究成果和学术奖励情况

1, Guihua Chen, Zhang-Jie Shi*. Privileged strategies for direct transformations of inert aliphatic C–H bonds, National Science Review, 2014, 1, 172.

2, Guihua Chen, Kang Chen, Zhang-Jie Shi*. Asymmetric allylic alkylation of alkene through direct C (sp3)-H functionalization, ChemCatChem. 2013, 5, 1289.

3, Guihua Chen, Jiangyang Gui, Peng Cao, Jian Liao*. Chiral sulfoxide-olefin ligands: tunable stereoselectivity in Rh-catalyzed asymmetric 1, 4-additions, Tetrahedron 2012, 68, 3220.

4, Guihua Chen, Junwei Xing, Peng Cao, Jian Liao*. Rh / chiral sulfinylphosphine catalyzed asymmetric 1, 4 – addition of arylboronic acids to chalcones, Tetrahedron 2012, 68, 5908. (Highlighted by Synfacts, 2012, 986).

5, Guihua Chen, Jiangyang Gui, Liangchun Li, Jian Liao*. Chiral sulfoxide-olefin ligands: completely switchable stereoselectivity in rhodium-catalyzed asymmetric conjugate additions, Angew. Chem. Int. Ed. 2011, 50, 7681. (Hot paper, Highlighted by Synfacts, 2011, 1193; Chin. J. Org. Chem. 2011, 31, 1961).

6, Feng Lang, Guihua Chen (co-first author), Liangchun Li, Junwei Xing, Fuzhong Han, Linfeng Cun, Jian Liao*. Rhodium-catalyzed highly enantioselective addition of arylboronic acids to 2-nitrostyrenes by tert-butanesulfinylphosphine ligand, Chem. Eur. J. 2011, 17, 5242. Highlighted by Synfacts, 2011, 882).

7, Li-Sheng Zhang, Guihua Chen, Xin Wang, Qing-Yun Guo, Xi-Sha Zhang, Fei Pan, Kang Chen, Zhang-Jie Shi*. Direct borylation of primary C-H bonds in functionalized molecules by palladium catalysis, Angew. Chem. Int. Ed. 2014, 53, 3899.

8, Xiangyang Zhang, Guihua Chen, Jibing Liu, Jian Liao*. Rhodium-catalyzed Michael addition of arylboronic acids to 3-alkylenyloxindoles: asymmetric synthesis of functionalized oxindoles, Tetrahedron Lett. 2012, 53, 438.

9, Jiangyang Gui, Guihua Chen, Peng Cao, Jian Liao*. Rh (I)-catalyzed asymmetric addition of arylboronic acids to NH Isatins, Tetrahedron: Asymmetry 2012, 23, 554.

10, Junwei Xing, Guihua Chen, Peng Cao, Jian Liao*. Rhodium-catalyzed asymmetric addition of arylboronic acids to indolylnitroalkenes, Eur. J. Org. Chem. 2012, 1230.

11, Jibing Liu, Guihua Chen, Junwei Xing, Jian Liao*. tert-Butanesulfinylthioether ligands: synthesis and application in palladium-catalyzed asymmetric allylic alkylation, Tetrahedron: Asymmetry, 2011, 22, 575.

12, Fuzhong Han, Guihua Chen, Xiangyang Zhang, Jian Liao*. Chiral heterodisulfoxide ligands in rhodium-catalyzed asymmetric 1, 4-addition of arylboronic acids to chromenones, Eur. J. Org. Chem. 2011, 2928.

13, Yongming Chuan, Guihua Chen, Jiuzhi Gao, Hui Zhang, Yungui Peng*. A facile direct anti-selective catalytic asymmetric Mannich reaction of aldehydes with preformed N-Boc and N-Cbz imines, Chem. Commun. 2011, 47, 3260.

14, Yongming Chuan, Guihua Chen, Yungui Peng*. Highly enantioselective Michael addition reactions in water catalyzed by an insoluble MPS-supported 4-sulfonamidyl prolinol tert-butyldiphenylsilyl ether, Tetrahedron Lett. 2009, 50, 3054. (Highlighted by Synfacts, 2009, 926).


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